Showing posts with label Mustard. Show all posts
Showing posts with label Mustard. Show all posts

Tuesday, October 2, 2012

7 December 2011 – Imagination and the toxic terrorist

Colleagues,

Consider, for a moment, these two pictures, and the attached deduction:



Congratulations - you've finished the Internet.

I'm going somewhere with this, trust me.

One of the perennial topics at the OPCW these days - and for that matter, in defence and public safety departments everywhere - is the question of chemical terrorism.  For the record, the last significant terrorist attack involving a chemical weapon occurred in 1995.  It was perpetrated by Aum Shinrikyo, and featured poor-quality sarin dispersed using a remarkably ineffective methodology.  Still, 12 people were killed and 5000 sickened by the attack.

More recent incidents have been considerably less effective. On 20 February 2007, for example, a tanker truck carrying chlorine gas exploded outside of a restaurant in the Iraqi town of Taji, a predominantly Sunni settlement some twenty kilometres north of Baghdad.  While some initial reports suggested that the truck may have struck a roadside improvised explosive device (IED), the Iraqi Government subsequently confirmed that the truck had been converted into a vehicle-borne chemical IED by the addition of a small bomb located next to the pressurized chlorine tank.  Six people were killed and approximately 150 injured, both by the initial blast and by subsequent exposure to chlorine gas.  No Coalition personnel were harmed in the attack.

This latter incident had two interesting characteristics.  First, it provided evidence of the evolution of insurgent tactics in Iraq, as previous attempts to employ improvised chemical weapons had focussed either upon producing “home-made” chemical agent (which failed miserably), or making use of the detritus of Saddam’s chemical weapons programs (e.g., attempting to disperse old nerve or mustard agent shells by detonating them with external explosives - which also failed miserably).  Second, it demonstrated a far better understanding of the threat posed by common, high-production-volume toxic industrial chemicals than had hitherto been the case amongst international jihadists, who had to date focussed a great deal of time and effort attempting to produce small quantities of traditional chemical warfare agents or biological toxins, or to weaponize rare and exotic chemical compounds for use in improvised chemical weapons or explosives.   The Surge helped damp down the violence, and while IED attacks and suicide bombings have continued in Iraq and elsewhere, there have been no repetitions of the chlorine attacks.

The deadliest terrorist attack using industrial chemicals occurred on 11 September 2001, of course, and the chemical involved - aviation fuel - was fairly prosaic.  Over the course of the subsequent half-decade, a number of potential attacks were thwarted by police and domestic intelligence services throughout the Western world; few were even slightly successful.  Until the 20 February 2007 chlorine attack, the successful ones all shared one element in common: they employed manufactured chemical explosives, or used easily-obtainable chemicals to produce improvised chemical explosives.  Similarly, many of the unsuccessful attacks appeared to share certain characteristics differentiating them from more lethal and destructive events.

Makeshift CBW.  First, some of the unsuccessful attacks appeared to be disproportionately focused on employing makeshift chemical or biological weapons (CBW).  Producing, weaponizing and effectively disseminating a CBW agent requires precise application of an array of exact sciences, posing daunting challenges to amateurs.  Aum Shinrikyo, for example, carried out at least two attacks using home-made sarin nerve gas, and at least one using home-grown anthrax.  Despite access to trained scientific personnel, virtually unlimited funding, a highly permissive security environment, and lax policing by officials worried about violating the patina of religion employed by Aum to conceal their activities, the perpetrators failed to produce the intended high casualty count.  Even with the widespread proliferation, particularly via the Internet, of detailed information on the production and deployment of CBW agents, groups lacking specialized scientific expertise in the field of chemical or biological weapons appear thus far to have been unable to overcome the hurdles.

Late in 2003, for example, London police uncovered a plan by an Islamic terrorist cell to employ the biological toxin ricin in terror attacks.  Ricin, despite its ease of production and high toxicity, is difficult to disperse and is simply not an effective weapon.  Canadian, British and American scientists conducted extensive experiments with ricin in a variety of munitions and dissemination devices during and after the Second World War, eventually abandoning it in favour of the more reliable nerve agents.



"Ricinis Communis" - the Castor Bean plant

Other plots have been even more exotic.  On 6 April 2004, British police foiled what appeared to be a plot to use osmium tetroxide as a chemical weapon.  From a technical perspective, osmium tetroxide makes a poor weapon; a crystalline solid with a melting point of 42° C, it is unlikely to produce, even through sublimation, a significant vapour mass, which is the most important operational criterion for an agent designed to injure or kill through inhalation.  The other option for dissemination – formation of a respirable aerosol by explosive dissemination – is a much more challenging technical problem, and given osmium’s propensity to act as an explosive catalyst, explosive dissemination would likely cause the agent to combust and disperse quickly.  Experts in chemical toxicity consulted by the media in the wake of the arrests fell into two distinct groups: those who noted the absolute toxicity of osmium tetroxide and were very concerned by the alleged incident; and those who noted its toxicity in comparison to modern chemical warfare agents, such as Sarin or VX, or to other less toxic, but more widely available, industrial compounds, and were rather less concerned.


Osmium tetroxide - not exactly a "high production volume" chemical

Toxic industrial chemicals.  This latter group of chemical experts tended to consider the incident in the broader context of comparative hazards and risks.  There is a vast array of industrial chemicals more toxic than osmium tetroxide (or more acidic, caustic, explosive or carcinogenic), most of which are readily obtainable in far larger quantities.  Virtually all of them are also considerably cheaper.  According to one UK report, osmium tetroxide may be obtained over the internet at a price of ₤17 per gram, making it twice as expensive as pure gold (and even kilogram quantities would likely be insufficient to generate a significant toxic hazard over a large area; using it to poison people would be like a footpad bludgeoning his victims with a Faberge egg).  By contrast, less exotic industrial chemicals like hydrogen fluoride, chlorine, sulfuric acid, dimethylamine, hydrogen sulfide, phosgene and sulfur dioxide are all produced worldwide in enormous quantities, and are shipped virtually everywhere by train-car and tank-truck – including across Canadian rail and highways.

Comparative risk is the key component in analyzing the hazard posed by toxic industrial chemicals.  Osmium tetroxide – based inter alia on its toxicity (high), how often it is shipped (infrequently), how much is shipped (very small quantities) and whether it has ever featured in an industrial accident or terrorist attack (it has not) – was recently assigned an overall risk value of 6 on a scale of 1 to 15 by a joint CANUKUS scientific board.  This makes it about 1560th on a list of nearly three thousand industrial chemicals evaluated by the board.  The same group rated sodium hydroxide, a highly caustic and very common industrial chemical, as 231st and assigned it a risk value of 10, noting that it ranked as one of the ten most common chemicals involved in industrial accidents.  By way of comparison, aviation fuel is number ten on the same list; and gaseous chlorine, number two.

These and hundreds of thousands of tons of equally hazardous industrial chemicals are shipped across North America via railroad, highway and inland waterway on a daily basis.  9/11 killed thousands using aviation fuel.  The 2004 Madrid train bombings killed hundreds with conventional explosives.  A similar attack against a train traversing a major city while carrying a thousand tons – a mere five tanker cars – of chlorine, hydrogen fluoride, hydrogen sulfide, dimethylamine, or an organophosphorous pesticide like parathion (or any of dozens of other highly toxic compounds) could, with a favourable wind, kill thousands.

The threat posed by toxic industrial chemicals is severe.  It would be far easier for terrorists to obtain a large quantity of a highly toxic (or for that matter, highly flammable) industrial chemical than to acquire even a few kilograms of an exotic substance like osmium tetroxide.

PSYCHO-ANALYZING THE 'TOXIC TERRORIST'

In view of the ready availability of large quantities of more common hazardous substances, one wonders why some terrorist groups appear to be concentrating on complex operations featuring exotic and unpredictable compounds unlikely to have the same impact as even a primitive improvised explosive device.  Either the individuals and groups planning these attacks are deluded as to the probability of success, or their motivation, goals and modi operandii differ significantly from those of their ideological brethren.  Presuming incompetence leaves no role for further analysis, though, and is in any case dangerous; a more prudent assessment may be that different organizations are following different operational philosophies.

Some groups appear to favour high-casualty operations featuring simple, proven technologies (improvised explosive devices, car bombs, hijacked aircraft) conducted by individuals prepared for and seeking martyrdom.  This approach appears to be shared by the more nihilistic of the Islamic terrorist organizations, including some Palestinian terrorist groups, the 9/11 hijackers, the various truck- and car-bombers operating in Iraq, the perpetrators of the railway blasts in Madrid and the would-be assassins of Pakistani President Musharraf.  Al Qaeda, the Tamil Tigers and numerous Palestinian terrorist organizations have enjoyed considerable success with this approach.

By contrast, other groups appear to favour a competing and thus far ineffective operational methodology – one characterized by complex operations featuring exotic substances based on unproven, experimental technologies which, even if successful, are unlikely to result in vast numbers of casualties.  The individuals caught in the course of staging these operations appear to be more likely to plan for their own escape, and may therefore be less inclined to seek “martyrdom”.  Given that these attacks appear to be perpetrated by a more educated class of individual, this may represent an inverse relationship between intelligence and willingness to become at martyr (as opposed to merely advocating martyrdom).  Additionally, in view of the fact that, notwithstanding the number of times this has been tried, a noteworthy chemical or biological attack has yet to be carried out, these groups also appear to be more likely to be caught.  In view of the fact that informants are reportedly playing a part in successful investigations, this category of attack seems to be conducted by a less dedicated class of individual – or at the very least, one reliant upon a wider network of actors, and perhaps less concerned with maintaining operational security. 

Many terrorists, of course, fall outside of this admittedly simplistic categorization.  The Bali bombers, for example, used a traditional improvised explosive approach, but apart from one member, appear to have made allowance for their own survival.  Similarly, the 2001 anthrax attacks in the United States employed both an exotic agent and a delivery method highly unlikely to cause mass casualties – but this attack was carried out by a disgruntled US government employee.  And pulling it off took an employee who had high security clearance, access to virulents bioagent strains, and more than a decade's experience as a biowarfare scientist.

Our principal enemy, international jihadism, seems to be plagued by a competency gap.  Despite the jihadists' obvious interest in employing weapons of mass destruction, they appear to lack even the rudimentary skills and knowledge necessary to obtain, weaponize and effectively deliver a CBW attack.  This may be due to any (or all) of a number of factors, including:

·        the capture or killing of a significant proportion of the educated, intelligent and scientifically literate leadership during the war in Afghanistan, the Iraq War, and subsequent worldwide policing and security sweeps (this may be particularly true with respect to al Qaeda);

·        the loss of Afghanistan (and for Ansar al-Islam, of Iraq) as a pied-à-terre and training ground has likely forced many of the survivors into constant movement in order to avoid death or capture, preventing them from accumulating the laboratory infrastructure and stockpiles of chemicals required to stage an attack; (note A) and

·        the fall of Saddam, allied restriction of the Afghan drug trade, Libya’s renunciation of both WMD and terrorism, increasing international scrutiny of Saudi Arabia, Iran and Syria, and the progressive tightening of controls on funding to terrorist organizations may be severely constraining their financial and logistic resources.(note B)

These and other constraints imposed by the “War on Terror” may have induced the opposition into hasty attempts to conduct ill-conceived operations.

Other explanations should also be considered.  Since 9/11, the Western media (abetted, to be sure, by government overuse of highly imaginative threat matrices) has succeeded in creating an atmosphere of apprehension, especially with respect to the potential use by terrorists of weapons of mass destruction.  The 2001 anthrax attacks in the US and the resulting panic likely taught our adversaries an important lesson regarding the susceptibility of Western publics to WMD-induced hysteria.  Indeed, this is almost certainly why Ayman al-Zawahiri once claimed that al Qaeda had acquired a “smart [nuclear] briefcase bomb” from disaffected Russian scientists.(Note C)  Given variable public sensitivity to WMD issues (and, by contrast, public indifference to industrial accidents, at least those short of the Bhopal scale), a terrorist attack that featured dispersion of an unfamiliar substance such as osmium tetroxide would be likely to generate panic to a degree that a much larger and therefore much more dangerous dispersion of a less exotic compound like caustic soda or ammonia would not.  It may therefore be useful to draw a distinction between two varieties of WMD-seeking terrorist: the calculating type hoping to terrorize in order to modify the behaviour of the target state; and the more recent, and more dangerous, Islamic nihilists, whose interest in WMD lies not in their potential to terrorize, but rather to kill large numbers of people.

SO WHAT?

We haven't seen the end of toxic terrorism.  While Osama bin Laden is no longer among the vertical, in 1998 he declared the acquisition and use of CBW a religious duty for muslims,(note D) and later requested and received a fatwa, issued by Saudi Sheikh Nasi bin-Hamid al-Fahd, condoning the use of CBRN weapons against non-Muslims.(note E)  There will be more of this, and if the jihadists see the light and focus on TICs instead of the unusual stuff, our problems are going to multiply.  The volume of chemical transfers is increasing, and new technologies like microsynthesis are making rapid production of small quantities of exotic, even supertoxic, chemicals easier than ever before.  Thus far the jihadists appear to have focused their efforts on large-scale attacks using more traditional, reliable means; but they are still trying to get their hands on supertoxic chemicals that industrialized states consider "chemical weapons."  Lack of success in this area suggests that it is probably only a matter of time until they turn their attention to the possibilities offered by the enormous volumes of toxic industrial chemicals produced and traded annually.  When they do, their operational patterns of behaviour suggest that they will eschew small-scale, exotic plans based on unpredictable, difficult-to-obtain compounds, and focus instead on large-scale, simple operations featuring hazardous chemicals that are available widely and in large quantity. 

To put it another way, crashing a VBIED into a building requires that you steal a V and build an IED.  Crashing a tanker full of toxic, caustic, acidic, flammable or explosive chemicals into a building requires only that you steal the right truck.  Combining both methods – a small bomb with a truckload of toxic chemicals – could greatly magnify the impact of such an attack, especially if operationally-savvy terrorists researched the properties of the chemicals they planned to steal, and made the most of geographic and meteorological conditions to conduct a release at the most damaging time and place.  This isn't rocket science; militaries have been doing it since 1915.


Accidental chlorine tanker derailment, Graniteville S.C., January 2005
5000 evacuated, 1450 hospitalized, 550 injured, 9 killed

Western nations should be exploring why the competent jihadists have yet to pursue this course of action.  The answer might tell us how much time we have before they figure it out.  Instead, what are we doing?  Worrying about exotic threats like ricin, osmium tetroxide, and whether a bunch of guys who haven't been able to figure out how to release chlorine as effectively as the Germans did at St. Julien are going to be able to cook up a batch of VX in somebody's bathtub without poisoning themselves first.  Those kinds of exotic threats are sexy, and they attract all sorts of press and (therefore) CT funding; but they're unrealistic, and they're nowhere near as potentially damaging as one guy who nabs a truck carrying chlorine, caustic soda or propane, and slams it into the Centre Block.  If the 20 February 2007 chlorine attack is any indication, maybe they're already starting to get it.

Which brings me back to the photo montage at the beginning of this message, and its disturbing deduction about the topology of the theoretical Hitler-Worf facial hair overlap.  My point is simple, and is applicable to separating realistic threats of chemical terrorism from wild-eyed fantasies about homemade VX and osmium tetroxide bombs: just because something is technically possible, that doesn't mean it's likely

Cheers,

//Don//

Notes

A) Quillen notes, “Clearly, the al-Qaeda CBRN programs that existed in Afghanistan under the Taliban were at least temporarily disrupted by the 2001 US-led invasion”.  Chris Quillen, “Three Explanations for al-Qaeda’s Lack of a CBRN Attack”, Terrorism Monitor, Vol. 5, No. 3 (15 February 2007).

B) That said, unless one is trying to legitimately purchase large quantities of highly expensive compounds such as osmium tetroxide, the resources required to stage a successful chemical attack are not great.

C) No such proliferation occurred, and indeed, it is questionable whether such a weapon ever existed.

D) Bin Laden’s declaration was delivered in the course of an interview with Jamal Isma’il in December 1998.  It was rebroadcast by al-Jazeera in September 2001.

E) Shiekh Nasir bin Hamid al-Fahd, “A Treatise on the Legal Status of Using Weapons of Mass Destruction Against Infidels”, May 2003 [http://www.carnegieendowment.org/static/npp/ fatwa.pdf].

Wednesday, May 16, 2012

19 May 2011 – Chemical Weapons Destruction update

Colleagues,

Between spending most of the past week writing a paper on the status of Libya’s chemical weapons (CW) destruction process in the context of the current crisis in that country, and wasting two fantastic hours last Saturday watching The Destroyer melt Acuras with his face, the word “destruction” has been on my mind a lot lately. 



Figure 1 - In Asgard, they understand that incineration is far superior to hydrolysis as a CW destruction methodology


So it’s not surprising that, whilst perusing the riveting Gossip and Style sections of the Salt Lake Tribune on Tuesday last, a headline all but jumped out at me: “Last of bulk mustard gas destroyed at Deseret Chemical Depot.”(Note A)  This naturally drew my attention away from the neighbouring article, which described the remarkable case of a chap ingesting his 25,000th Big Mac a mere 39 years after consuming his first, and caused me to dig into my back-files on the US chemical weapons programme to refresh my memory.

Deseret is one of the facilities that’s a plague to dabblers in the CW world, because it’s one of two names applied to what is essentially the same place.  Technically, the name of the facility is the ”Deseret Chemical Depot”, but due to the fact that it’s associated with the Toelle Army Depot and is located in Toelle, Utah, it tends to get referred to in international fora, and from time to time even by the Americans, as “Toelle” (pronounced “Two-Ella”).  Although not the oldest CW-related site in the US (that honour belongs to Edgewood Arsenal in Maryland), Toelle is far and away the largest.  When the Chemical Weapons Convention entered into force in 1997, the depot held more than 13,600 tons of CW agent - roughly half of the entire declared US stockpile - in close to a million different containers and projectiles. 


Figure 2: The US CW Stockpile at entry-into-force, 1997

The grand total of munitions stored at the depot was staggering:

H, HD, HT (Mustard)
105 mm artillery shells: 54,663
155 mm artillery shells: 63,568

GB (Sarin)
105 mm artillery shells: 798,703
155 mm artillery shells: 89,141
M-55 free-flight artillery rockets: 17,353

VX
155 mm artillery shells: 53,216
M-55 free-flight artillery rockets: 3,966
M23 land mines: 22,690

Additionally, the depot also held blister and nerve agent in one-ton bulk storage containers and spray tanks. 



Figure 2 - 1-ton containers of distilled mustard (HD) stored at the Deseret depot, 1998 (there’s more mustard in this picture than Libya has left in its stockpile)


Such a vast quantity of weaponry and toxic chemicals - much of it aging (some of the mustard dated to the Second World War, while the depot also held quantities of pre-WWII Lewisite, as well quantities of Tabun(GA) that had been captured from the Nazis during the War) - posed a wide variety of challenges to destruction.  Mustard, for example, tends to polymerize (thicken) in storage, becoming first gluey, then gelling, and finally taking on the consistency of a hockey puck.  This makes it impossible to destroy by hydrolysis, necessitating incineration.  However, due to the nature of production processes used at the time the mustard was synthesized, a good deal of it turned out to be contaminated with mercury, imposing much tighter emissions controls and necessitating the installation of very fine filters, scrubbers and electrostatic precipitators on the incineration equipment (and consequently pushing costs through the roof; at last report, the US CW destruction programme was projected to cost well over $40B by the time it is complete in a decade or so).  Different agents and weapons posed different problems; one-ton containers tend to be easy to drain and destroy, while artillery shells have to be defuzed and drilled first.  Land mines contain fuzes, too.  Worst of all were the M-55 rockets, which - because they have thin-walled aluminum bodies - tend to develop leaks, making them horrible to handle, and which contain fuzes, rocket motors, high explosives and batteries.  The technology that had to be developed to demilitarize VX-filled M-55 rockets was nothing short of staggering.

Unlike the Russians, the US tackled the hard stuff - the mines, shells and rockets - first, and left the easy stuff (the ton containers) for the end.  Completion of the bulk mustard destruction process therefore means that Toelle is getting near to the end of a programme that got underway in 1996, before the Convention even came into effect.  Only a small quantity of munitions remain to be destroyed, among them about 350 shells where the mustard was so badly polymerized that it was impossible to remove the agent from the projectiles.  Such problem cases tend to be destroyed by contained explosion in specially-built mobile destruction facilities.


Figure 4 - the US Army Chemical Materials Agency’s Explosive Destruction System (EDS) can safely detonate and decontaminate up to 6 CW projectiles at once

The staff at Deseret also plan to destroy the above-mentioned Lewisite and Tabun munitions by early next year.  Once this has been taken care of, all that will remain at Deseret are the “solid waste management pits” - old munitions dumps dating from decades ago, when munitions were destroyed in the open air (which is now forbidden by the Convention).  Most of the personnel will be transferred to the Toelle Army Depot, and the destruction facility will be closed.

The impending closure of the Deseret/Toelle CWDF brings up an interesting problem that the States Parties to the Convention will have to wrestle with at this year’s Conference of the States Parties (coming up in Nov-Dec 2011 in The Hague).  In 2009, there were 13 CW destruction facilities (CWDFs) in operation around the world: one in India, four in Russia, and eight in the US.  India has since completed its destruction programme and closed its CWDF, and the destruction operations at Kambarka in Russia, and at Newport, Indiana and Dugway, Utah have likewise come to a close.  Libya began destroying chemical precursors at its CWDF (at Rabta, with three sub-sites at Ruwagha east of Waddan, about 700 km southeast of Tripoli) last May, and commenced mustard destruction there last fall, which was going well up until the hydrolysis equipment broke down and repair parts could not be obtained due to the present crisis.

The decline in destruction activities is inevitable as CW stockpiles continue to fall; more than 62% of all declared CW have been destroyed to date; and it is relevant because the vast bulk of inspection activity conducted by the OPCW - more than 85% of inspector-days - is related to continuous monitoring and verification at the destruction facilities.  Article VI (or “Industry”) verification accounts for only about 1/6 of the Organization’s inspection activities.  Once all the weapons are gone, not nearly as many inspectors will be needed.

But it won’t be a smooth decline.  The final deadline for destruction of all CW is 29 April 2012.  Both Russia and the US have advised that they are likely to miss this deadline, probably by many years (and it now looks like Libya could miss it, too).  The difficulty from the perspective of the Organization is that CWDFs that have been operating for many years now are coming to the end of their programmes, while some others - for example, at Kizner and Pochep in Russia, and at Blue Grass, Arkansas and Pueblo, Colorado in the US - are still under construction, and in some cases won’t commence operations for years.(Note B)  As a result, there is going to be a gap of several years during which there will be a much smaller need for continuous monitoring and verification at CWDFs than there has been for the past 14 years.  This means that the OPCW is going to have to cope with direction from the States Parties to significantly downsize both the Inspectorate and its operational budget for 2-3 years (or even longer, if construction on new CWDFs proceeds slowly) - and then will have to expand both again once the new facilities begin destruction operations.
This won’t be easy; trained chemical munitions specialists are no longer common, because there are no longer any large CW programmes in the world.  The generation that supplied inspectors to UNSCOM, UNMOVIC and the first generation of the OPCW is retiring.  The OPCW now has to make inspectors instead of simply hiring them with years of experience.  Unfortunately, there is no alternative to downsizing; States Parties will not accept having the Inspectorate grossly underemployed for several years; and although it would be highly desirable to reorient allocated inspector-hours to Industry verification, for political reasons this would be impossible.  Every year the Technical Secretariat attempts to increase the number of Industry inspections by 5-10 (there were 208 Article VI inspections in 2009, but more are required, the argument being that the true threat of CW proliferation is no longer at CW storage and destruction facilities, but rather at small, flexible, multipurpose batch production plants), and every year it takes days of intensive wrangling between States Parties to agree on the total number of Article VI inspections - generally with the Western European and Other Group (WEOG) demanding more inspections, and the Non-Aligned Movement, led or goaded on by India, Cuba, South Africa, Iran and China, demanding fewer inspections (often as leverage to wring more Article XI, or “Economic and Technological Development”, money out of the Organization - but that’s a topic for another CoP).  So simply quintupling or sextupling the number of Industry inspections to keep the Inspectorate busy, however desirable it might be, is just not an option.

The wrap-up of the bulk mustard destruction programme at Deseret illustrates how time moves on, things change, and international organizations - if they want to remain relevant - have to change with them.  Dealing with the downsizing of the Inspectorate, a significant trimming of the Organization’s budget (in 2009, verification accounted for €34.9M of the Organization’s expenditures of €71.3M - Note C), and the impending non-compliance of the US, Russia and possibly Libya with the Convention’s destruction obligations, are sure to make for fascinating fodder at this year’s Conference of States Parties. 
A good thing, too, because as some of you probably know from first-hand experience, Den Haag in December is a lot more like Jotunheim than Asgard.

Cheers,

//Don//

Notes
A) http://www.sltrib.com/sltrib/news/51823485-78/chemical-depot-weapons-agent.html.csp
B) REPORT OF THE OPCW ON THE IMPLEMENTATION OF THE CONVENTION ON THE PROHIBITION OF THE DEVELOPMENT, PRODUCTION, STOCKPILING AND USE OF CHEMICAL WEAPONS AND ON THEIR DESTRUCTION IN 2009, OPCW, C-15/4, 30 November 2010, 5.
C) ibid., 63.

Tuesday, March 27, 2012

25 February 2011 – North African turmoil, CW worries

Colleagues,

The events of the past few weeks in North Africa make me wonder about the security of the chemical weapons (CW) programmes of the states that are presently melting down.  Both Egypt and Libya have CW.  Egypt, because it never joined the Chemical Weapons Convention, has never been required to make a declaration; but Cairo almost certainly has stockpiles of mustard and possibly G- and V-agents, and probably has the capability to produce more advanced CW.  For those who are interested, I’ve attached a paper - almost 13 years old, now - by Dany Shoham, from the 1998 Spring-Summer edition of the Non-Proliferation Review, that gives a comprehensive overview of Egypt’s chemical and biological weapons programmes at time of writing, including details of the support Cairo has supplied to other CBW proliferators, like Syria and pre-liberation Iraq.

We know a little more about Libya.  Shortly after the US Army pulled Saddam out of his furnished septic tank in December 2003, Qadafy, having recently been caught trafficking in nuclear what-nots by the Proliferation Security Initiative, turned states-evidence, voluntarily joining the CWC and declaring tons of CW agents, precursors, and unfilled munitions.  The OPCW conducted its first visit to Libya in February of 2004 and destruction got under way the same month, beginning with the easy stuff: the Category 3 chemical weapons, Libya’s unfilled munitions (mostly, as I understand it, empty aircraft bombs that could have been filled either with mustard or nerve agent).  These were destroyed via the highly technical process of lining them up on the sand and driving a bulldozer over them.  That part of the program was complete by March 2004.  Libya submitted its initial declaration immediately thereafter, declaring approximately 23 metric tonnes of mustard gas, one inactivated CW production facility, and two CW storage facilities.  No filled munitions were declared. (Note A)

The “inactivated CWPF” quickly became a bone of contention.  Known as al-Rabta, Libya soon requested permission to convert the facility into a pharmaceutical plant.  However, according to paragraph 72 of Part V of the Verification Annex, conversion of any CWPF for “purposes not prohibited by the Convention” must be completed not later than six years into entry after force of the Convention.  As the Convention entered into force on 29 April 1997 and Libya did not join until March 2004, the deadline for conversion was automatically missed.  This caused the Conference to approve a Technical Change to the Verification Annex, inserting paragraph 72bis establishing that conversion deadlines for states parties entering after the six year deadline to be set by the Executive Council.  This was only the second Technical Change ever made to the Convention (the first being a Canadian-instigated change - the insertion of paragraph 5bis into Part VI of the Verification Annex eliminating the requirement for 30-day advance notification of transfers of 5 milligrams or less of Saxitoxin for medical/diagnostic purposes).  Libya stated that it had completed conversion of the two separate facilities at al-Rabta in 2009.

Destroying Libya’s CW stockpile has been a lot trickier.  By the end of 2009, Libya had not destroyed any of its Category 1 chemical weapons (agent and precursors) and only 39% (551 tonnes) of its Category 2 CW.  The Categories, incidentally, are a declaration mechanism designed to assist States Parties and the Inspectorate in prioritizing declared CW for destruction.  Laid out in paragraph 16 of Part IV(A) of the Verification Annex, the categories are:

·          Category 1 - CW based on Schedule 1 chemicals (the traditional warfare agents) and their parts and components

·          Category 2 - CW based on all other chemicals and their parts and components

·          Category 3 - Unfilled munitions and devices, and equipment specifically designed for use directly in connection with employment of CW

Bottom line, Libya still has many tonnes of mustard and an awful lot of G-agent precursor chemicals (the Cat 2 materials, mostly phosphorous compounds) still kicking around.  This is because impoverished and technically unsophisticated countries tend to have difficulty coming up with a destruction plan that does not involve burial, sea-dumping or open-air burning, all of which are prohibited by the Convention.  Incineration and neutralization by hydrolysis are both acceptable methods, provided appropriate environmental constraints are observed, but they take a certain degree of scientific and engineering competence.  I’ve heard stories about Libya’s destruction programme over the past year that would curl your hair - the phrase “and then they set the desert on fire” came up.  Fascinating, so long as you’re not downwind.

In 2009, Libya’s mustard was reloaded from small storage canisters into new tanks for shipment to the destruction facility; 22.3 tonnes of it, anyway.  The reloading process demonstrated one of the more unpleasant qualities of mustard - its tendency to polymerize in storage, forming a gooey “heel” with all of the toxicity and mutagenic properties of pure mustard, but with a consistency varying from that of molasses to that of tar to that of a hockey puck.  2.5 tonnes of this horrid goop remained in the original containers. You can’t hydrolyze polymerized mustard unless you can make it dissolve first, and that’s no easy task even with potent organic solvents.  This is why smart people prefer high-temperature incineration.  It’s the chemical equivalent to “nuking the site from orbit” - it’s the “only way to be sure.”

Interestingly, Wikileaks has provided some corroboration of the problems Libya is experiencing with its CW programs.  According to one of the released secret cables (reported in The Telegraph), the head of Libya’s CW destruction programme, Dr. Ahmed Hesnawy (who is also the former head of its CW production programme), told the US Embassy in Tripoli in  late 2009 that a “grassroots environmental campaign” and “civil defence concerns about possible leaks” had caused “all hell to break loose” with the programme.  The embassy’s comments on these explanations were sceptical about the environmental movement, but gave credence to the concern about leaks: ”Given tight Libyan Government controls over national security facilities and programs, we find it hard to believe that a grassroots movement could affect Libyan policy or action on a sensitive program such as the Rabta facility”; and “The UK DCM, who visited the storage facility earlier this year, told P/E Chief that the containers currently housing the material were in fact leaking when he observed them.” (Note B)

Libya’s difficulties prompted Tripoli to request an extension, and in December 2009, the Fourteenth Conference of the States Parties approved an extension to 15 May 2011 (C-14/DEC.3, 2 December 2009.  A deadline of 31 December 2011 was set for Libya’s Cat-2 CW, approved by the 11th Conference in 2006).  Intermediate deadlines were extended by the 15th Conference last December.  There was already some doubt whether these deadlines were achievable; now, they seem unlikely to be achieved at all.  Libya could easily miss the final destruction deadline (29 April 2012), along with the US and Russia, as the destruction operations have to be carried out under continuous monitoring and verification by the OPCW, and the OPCW cannot send its inspectors into a civil war.

But at least the bombs were crushed first.  Given Colonel Mo’s demonstrated propensity for using air-to-surface weapons for crowd control, we should be grateful for that small mercy.

Cheers,

//Don//

Notes

(A) http://www.opcw.org/news/article/libya-submits-initial-chemical-weapons-declaration/

(B) http://www.telegraph.co.uk/news/wikileaks-files/libya-wikileaks/8294660/LIBYAS-CHEMICAL-WEAPONS-DESTRUCTION-CHIEF-DEFENDS-EXTENSION-REQUEST.html





Saturday, March 17, 2012

26 August 2010 – Tweaking the Pot

Colleagues,

A news article about the UN’s Clean Development Mechanism caught my eye this week because it reminded me of a similar problem that arose at the OPCW a few years back.

Perhaps the single most challenging aspect of keeping a disarmament and non-proliferation agreement like the Chemical Weapons Convention on the rails is ensuring that it achieves its objectives with the minimum possible impact on legitimate industry.  Squaring that circle is extraordinarily complex and requires a comprehensive, in-depth knowledge and appreciation of how the global chemical industry works, and how its myriad components fit together.  This sort of balancing act is not possible in every area of endeavour; the problems associated with deconflicting treaty requirements and the needs of the domestic and international biotech and pharmaceutical industries, for example, were the key factor in the failure of the 2001 BTWC Review Conference.  In the chemical world, juggling competing interests often means getting down into the nitty-gritty of how chemicals are actually produced.

4 August 2010 – Getting Rid of ‘Grandpa’

Colleagues,

The US Army Chemical Demilitarization programme reached noteworthy milestone yesterday when the Umatilla Chemical Agent Disposal Facility (UMCDF) at Hermiston, Oregon, destroyed the oldest container of sulphur mustard ever stored at the Umatilla Depot.  Bulk mustard agent is generally stored in “ton containers”.  These are steel tanks gel capsules that are about the size of an industrial water heater.  The ton container in question, which the facility’s staff had nicknamed “Grandpa”, was more than 70 years old.  It had been manufactured in 1940 and, in 1946, was filled with 1,768 pounds of HD (distilled sulphur mustard) at the Rocky Mountain Arsenal near Denver, Colorado.  Some time between 1962 and 1969, “Grandpa” was shipped to Umatilla where it was placed in storage - in a building that, in recent years, had come to be known as “Grandpa’s House”.